RADIOCARBON
DATING
The radioactive Carbon isotope ¹⁴C is a natural chronometer used in a very wide range of applications, among which Radiocarbon dating is the best known and widely used for the determination of the age of findings of organic origin up to about 50,000 years. The discovery of the ¹⁴C dating method by Libby in 1949 revolutionized both archaeology and geology, and later was applied in fields spanning from biomedicine to climatology, from hydrology to oceanography, from environmental physics to volcanology.

¹⁴C is a cosmogenic isotope, as it is produced by interactions induced by cosmic rays with atmospheric nitrogen (¹⁴N). Its abundance reaches equilibrium in the atmosphere and the biosphere, so that the ¹⁴C/¹²C isotopic ratio of all organisms is constant during their life, while after their death it decreases exponentially with a mean life of about 8,300 years. The measurement of its present value in the remains allows then the determination of the time passed since the cessation of Carbon absorption by the organism. This age is quoted in years “before present”, where present is conventionally 1950 AD. Its uncertainty, typically of the order of 20 years, may result in larger or smaller calibrated age ranges, depending on the behavior of the calibration curve in the relevant period.
ISOCORE performs since 2005 high-precision radiocarbon dating measurements of samples (such as wood , charcoal, seeds, shells, forams, bones, teeth , textiles, paper, peats, paleo soils, soil organic matter, tree-rings), mainly archaeological finds and artistic master-pieces. For most of these sample kinds a tiny amount (less than one milligram) of the raw specimen is needed, thanks to the use of the accelerator as an element of the mass spectrometer.
The radiocarbon dating is applicable to prehistoric or historic artifacts whose presumed age is prior 1700 CE, with a precision of ± 20 years. After that date, due to the so-called “Suess effect”, the method is not able to precisely distinguish among a dataset of different dates falling within the 1700 – 1955 CE interval. Moreover, thanks to anthropogenic production of ¹⁴C due to nuclear bomb testing in the atmosphere during the postwar period, the method is able to date, with higher precision (of the order of one year), a sample older than 1955 CE.


ISOCORE
STANDARD
PROTOCOLS
This treatment, used for most organic material types, such as wood, charcoal, seed, vegetal remains, peat, removes carbonates by hot HCl attack and humic acids by hot NaOH attack. The basic phase adsorbes the CO2 atmospheric so a final HCl attack is applied to remove it. The sample is rised until neutral, dried and ready for combustion. The duration and temperature of the treatment varies according to the fragility of the sample.

MATERIAL
GUIDELINES
|
Materials |
Required mass (mg) |
|
Wood |
10-40 |
|
Charcoal/Seed |
10-30 |
|
Shell/Forams |
10-20 |
|
Bone/Tooth Cremated bone |
500-2000 2000-3000 |
|
Textile/Paper |
20-40 |
|
Peat |
50-100 |
|
Paleosoil |
5000-8000 |
|
Soil Organic matter |
1000-2000 |
|
Tree-ring |
5-8 |
|
Mortar |
20000-30000 |
|
Bioplastic |
2-10 |









